Abstract

    Open Access Review Article Article ID: ABSE-5-113

    The new paradigm in thermodynamic formulation of electrolytic systems – A review

    Anna M Michałowska-Kaczmarczyk and Tadeusz Michałowski*

    The general property of electrolytic systems in aqueous media is presented. The linear combination f12 = 2∙f(O) – f(H) of elemental balances: f1 = f(H) for Y1 = H and f2 = f(O) for Y2 = O, is put in context with charge balance (f0 = ChB) and other elemental and/or core balances fk = f(Yk) (k=3,…,K) related to the system in question It is stated that f12 is (a) linearly independent on f0,f3,…,fK for a redox system, or is (b) linearly dependent on f0,f3,…,fK when related to a non-redox system. The balance f12 = 2∙f(O) – f(H) is the primary form of generalized electron balance (GEB), completing the set of equations needed for quantitative description of electrolytic redox systems, f12 = pr-GEB.

    Keywords:

    Published on: Aug 12, 2019 Pages: 19-60

    Full Text PDF Full Text HTML DOI: 10.17352/abse.000013
    CrossMark Publons Harvard Library HOLLIS Search IT Semantic Scholar Get Citation Base Search Scilit OAI-PMH ResearchGate Academic Microsoft GrowKudos Universite de Paris UW Libraries SJSU King Library SJSU King Library NUS Library McGill DET KGL BIBLiOTEK JCU Discovery Universidad De Lima WorldCat VU on WorldCat

    Indexing/Archiving

    Global Views

    Case Reports

    Peertechz Tweets

    Pinterest on ABSE

    Google Reviews 11